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Study on preparation and inclusion behavior of inclusion complexes between beta-cyclodextrin derivatives with benzophenone

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成果类型:
期刊论文
作者:
Deng, Shanxia;Liu, Huijun*;Qi, Caixia;Yang, Aohui;Li, Zhendong
通讯作者:
Liu, Huijun
作者机构:
[Deng, Shanxia; Yang, Aohui; Liu, Huijun; Qi, Caixia; Li, Zhendong] Univ South China, Sch Chem & Chem Engn, 28 Changsheng Rd West, Hengyang 421001, Hunan, Peoples R China.
通讯机构:
[Liu, Huijun] U
Univ South China, Sch Chem & Chem Engn, 28 Changsheng Rd West, Hengyang 421001, Hunan, Peoples R China.
语种:
英文
关键词:
Benzophenone;beta-Cyclodextrin derivatives;Inclusion complex;Thermodynamics studies
期刊:
Journal of Inclusion Phenomena and Macrocyclic Chemistry
ISSN:
1388-3127
年:
2018
卷:
90
期:
3-4
页码:
321-329
基金类别:
Hunan Provincial Innovation Foundation For Postgraduate [CX2017B523]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [11375084]; Nature Science Foundation of Hunan [2017JJ4046]
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
In the paper, the two chemically modified β-cyclodextrin derivatives of 4,4´-diaminodiphenyl ether-bridged-bis-β-cyclodextrins (ODA-bis-β-CD) and p-aminobenzenesulfonic acid-β-cyclodextrin (ABS-β-CD) were synthesized, and then these two β-cyclodextrin derivatives were respectively formed into inclusion complexes with benzophenone (BP) by co-precipitation method. The structure of the inclusion complexes were characterized by UV/vis spectroscopy, FT-IR spectroscopy, elemental analysis, 1H NMR spectroscopy and XRD. Spectral titration was pe...

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