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N and S dual-coordinated Fe single-atoms in hierarchically porous hollow nanocarbon for efficient oxygen reduction

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成果类型:
期刊论文
作者:
Cui, Linfang;Hao, Jie;Zhang, Yan;Kang, Xiaomin;Zhang, Jiujun;...
通讯作者:
Fu, Xian-Zhu;Luo, JL
作者机构:
[Luo, Jing-Li; Cui, Linfang; Luo, JL; Fu, Xian-Zhu] Shenzhen Univ, Coll Mat Sci & Engn, Guangdong Res Ctr Interfacial Engn Funct Mat, Shenzhen Key Lab Polymer Sci & Technol, 1066 Xueyuan Ave, Shenzhen 518055, Peoples R China.
[Hao, Jie] Chinese Inst Rehabil Sci, China Rehabil Res Ctr, Beijing Key Lab Neural Injury & Rehabil, Beijing 100068, Peoples R China.
[Zhang, Yan] Pingshan Translat Med Ctr, Shenzhen Bay Lab, Shenzhen 518055, Peoples R China.
[Kang, Xiaomin] Univ South China, Sch Mech Engn, Hengyang 421001, Peoples R China.
[Zhang, Jiujun] Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China.
通讯机构:
[Luo, JL ; Fu, XZ] S
Shenzhen Univ, Coll Mat Sci & Engn, Guangdong Res Ctr Interfacial Engn Funct Mat, Shenzhen Key Lab Polymer Sci & Technol, 1066 Xueyuan Ave, Shenzhen 518055, Peoples R China.
语种:
英文
关键词:
Aluminum-air batteries;Direct methanol fuel cells;Hierarchical hollow structure;N, S dual-coordinated Fe single-atoms catalysts;Oxygen reduction reaction
期刊:
Journal of Colloid and Interface Science
ISSN:
0021-9797
年:
2023
卷:
650
期:
Pt A
页码:
603-612
基金类别:
Shenzhen Science and Technology Program [KQTD20190929173914967, ZDSYS20220527171401003, JCYJ20200109110416441]; National Natural Science Foundation of China [220030412021CZ-1]; Special Fund for Basic Scientific Research of Central Public Research Institutes [2021CZ-1, 2022CZ-6]
机构署名:
本校为其他机构
院系归属:
机械工程学院
摘要:
Fe-, and N-co-doped carbon (FeNC) electrocatalysts are promising alternatives to Pt-based catalysts for oxygen reduction reaction (ORR); however, simultaneously enhancing their intrinsic activity and exposure of Fe active sites remains challenging. Herein, we report S-modified Fe single-atom catalysts (SACs) anchored on N,S-co-doped hollow porous nanocarbon (Fe/NS-C) for ORR. The unique hollow structure and large surface area of the SACs are favorable for mass/electron transport and exposure of Fe single-atom active sites. The as-prepared Fe/NS-C electrocatalysts display a high-efficiency ORR ...

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