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A new Schiff base fluorescent indicator for the detection of Mg2+ and its application to real samples

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成果类型:
期刊论文
作者:
Zhang, Qin;Wang, Hongqing*;Wang, Yuyuan;Jing, Pengfei;Luo, Aoheng;...
通讯作者:
Wang, Hongqing
作者机构:
[Wang, Hongqing; Jing, Pengfei; Huang, Qiao; Zhang, Qin; Luo, Aoheng; Wang, Yuyuan] Univ South China, Sch Chem & Chem Engn, 28 Changsheng West Rd, Hengyang 421001, Hunan, Peoples R China.
通讯机构:
[Wang, Hongqing] U
Univ South China, Sch Chem & Chem Engn, 28 Changsheng West Rd, Hengyang 421001, Hunan, Peoples R China.
语种:
英文
关键词:
Schiff base;Fluorescence probe;Mg2+;Detection
期刊:
Research on Chemical Intermediates
ISSN:
0922-6168
年:
2016
卷:
42
期:
8
页码:
6681-6693
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [11175080]; Science Foundation of Hunan Province Department of Education [12A117]; Hunan Provincial Innovation Foundation for Postgraduate [CX2015B399, CX2015B400]
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
A new Schiff base fluorescence probe, 3-Allylsalicylaldehyde salicyl-hydrazone (L), for Mg2+ was designed and synthesized. The fluorescence of the sensor L was enhanced remarkably by Mg2+ with 2: 1 binding ratio, and the binding constant was determined to be 1.02 x 10(7) M-1. Probe L had high sensitivity for Mg2+ in a solution of DMF/water (4: 1, v/v, pH 7.5), and the detection limit was 4.88 x 10(-8) mol/L. Common coexistent metal ions, such as K+, Na+, Ag+, Ca2+, Zn2+, Ba2+, Bi2+, Cu2+, Ni2+, Hg2+, Fe3+, and Al3+, showed little or no interference on the detection of Mg2+ in solution. The flu...

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