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Preparation of phosphinimide and its adsorption of uranium in aqueous solution

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成果类型:
期刊论文
作者:
Liu, Zengcheng;Wang, Zhongchao;Wang, Yanfei
通讯作者:
Wang, YF
作者机构:
[Liu, Zengcheng; Wang, Yanfei; Wang, Zhongchao] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
通讯机构:
[Wang, YF ] U
Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
语种:
英文
关键词:
Phosphinimide;Polymerization precipitation;Adsorption;Uranium(VI);Endothermy
期刊:
Research on Chemical Intermediates
ISSN:
0922-6168
年:
2024
卷:
50
期:
6
页码:
2897-2915
基金类别:
Scientific Research Fund of Hunan Education Department; National Natural Science Foundation of China [51803088]; [17C1360]
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
The phosphinimide materials described in this paper were synthesized by polymerization precipitation. The properties of complexes coordinated with metal ions can be used as adsorbents for the adsorption of radioactive elements by using ligands such as imide and phosphorus groups. Then, the synthetic phosphinimide was characterized in detail by FT-IR, SEM, EDS and XPS, and its morphology and structural changes were studied. In addition, the effects of the material on the removal of uranium(VI) from aqueous solutions at different pH, sorbent dose...

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