期刊论文

Shi, Wei-Qun

英文

Journal of Molecular Liquids

0167-7322

2020

299

112174

10.1016/j.molliq.2019.112174

This study was supported by the National Natural Science Foundation of China (Grant Nos. 11575212, 21876174, 11875058), Major Program of National Natural Science Foundation of China (No. 21790373), and the Science Challenge Project (No. TZ2016004). This study was also supported by the Project of State Key Laboratory of Radiation Medicine and Protection, Soochow University (No. GZK1201802). The results described in this study were obtained on the ScGrid of the Supercomputing Center, Computer Network Information Center of Chinese Academy of Sciences. This study was supported by the National Natural Science Foundation of China (Grant Nos. 11575212 , 21876174 , 11875058 ), Major Program of National Natural Science Foundation of China (No. 21790373 ), and the Science Challenge Project (No. TZ2016004 ). This study was also supported by the Project of State Key Laboratory of Radiation Medicine and Protection, Soochow University (No. GZK1201802 ). The results described in this study were obtained on the ScGrid of the Supercomputing Center, Computer Network Information Center of Chinese Academy of Sciences. Appendix A

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Separation of trivalent actinides (An(III)) and lanthanides (Ln(III)) is a pivotal step with respect to the treatment of nuclear waste based on the partitioning and transmutation (P&T) strategy, which is also extraordinarily challenging due to their similar coordination chemistry. The diethylenetriaminepentaacetate (DTPA) ligand has been demonstrated to possess selective separation ability toward An(III) over Ln(III) in aqueous media. Nevertheless, the extracted complexes of An(III)/Ln(III) with DTPA, and the origin of selectivity for An(II...