期刊论文

Ding, D.-X.(dingdxzzz@163.com)

中文

中国有色金属学报

1004-0609

2012

22

2

604-610

10.19476/j.ysxb.1004.0609.2012.02.040

国家自然科学基金资助项目（50774047） 湖南省教育厅科研项目（10C1180） 衡阳市科技局项目（2010ks32）

本校为通讯机构

以纳米Fe_3O_4磁性微粒负载啤酒酵母菌,制备一种新型铀吸附剂,考察其吸附铀的主要影响因素,即溶液pH值、铀初始浓度、吸附剂投加量及其粒度,分析吸附过程的反应动力学和等温吸附规律,并用扫描电镜和能谱仪分析吸附机理。结果表明:纳米Fe_3O_4负载啤酒酵母菌(NFSC)吸附铀的最佳条件是pH值为7.0,铀初始浓度为60 mg/L,NFSC加入量为50 mg,NFSC的最佳粒径为12 nm。NFSC对铀的吸附动力学较好地符合准二级动力学模型,相关系数为0.999 6;吸附等温线均能符合Langmuir和Freundlich等温线模型,说明该吸附体系是一个单层覆盖与多层吸附相结合的模式。扫描电镜和能谱图表明:NFSC吸附铀后表面形态发生变化,且吸...

A novel biosorbent was prepared by loading saccharomyces cerevisiae onto nano-Fe3O4 saccharomyces cerevisiae (NFSC), and the factors, including pH value, initial concentration, adsorbent dosage and adsorbent particle size, impacting the adsorption of NFSC on uranium were investigated. The kinetics and adsorption isotherm law were analyzed, and the mechanisms of uranium adsorption were discussed by SEM and energy spectrum analysis. The results show that NFSC has high adsorption rate on uranium at the solution pH of 7.0, the adsorbent dosage of 50 mg and the optimal NFSC particle size of 12 nm w...