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铀催化的氮气活化

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成果类型:
期刊论文
论文标题(英文):
Dinitrogen Activation by Uranium Complex
作者:
Tao, Xuebing;Yu, Jipan;Mei, Lei;Nie, Changming;Chai, Zhifang;...
作者机构:
[Tao, Xuebing; Nie, Changming] Univ South China, Sch Chem & Chem Engn, Hengyang 421000, Peoples R China.
[Mei, Lei; Chai, Zhifang; Shi, Weiqun; Yu, Jipan] Chinese Acad Sci, Inst High Energy Phys, Lab Nucl Energy Chem, Beijing 100049, Peoples R China.
[Chai, Zhifang] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Engn Lab Adv Energy Mat, Ningbo 315201, Peoples R China.
语种:
中文
关键词:
氮气活化;含铀金属化合物;低价态;配位化学
关键词(英文):
dinitrogen activation;uranium complex;low valence;coordination chemistry
期刊:
化学进展
ISSN:
1005-281X
年:
2021
卷:
33
期:
6
页码:
907-913
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21806167, 21925603]; Science Challenge Project [TZ2016004]; Youth Innovation Promotion Association of CAS [2017020]
机构署名:
本校为第一机构
院系归属:
化学化工学院
摘要:
氮气约占空气总体积的78%,是大自然赋予人类的宝贵资源。如何实现氮气转化为动植物可利用的含氮化合物,关系着人类的未来和社会的可持续发展。氮气活化,作为一个非常重要的研究领域,一直以来都是科学家面临的重大挑战。目前,低价铀金属有机化合物展现出良好的小分子活化能力。本综述主要介绍了含铀化合物对氮气活化的研究进展,并对其未来进行了展望。
摘要(英文):
Dinitrogen is the most abundant gas in the air (approximately 78% of the total air volume). which is a precious resource endowed by nature. How to make use of dinitrogen and transform it into useful nitrogenous compounds is important for humans and sustainable development of society. Dinitrogen activation. as a very important research field. has always been a major challenge. At present. low valent uranium complexes exhibit excellent performance in the small molecule activation. This review mainly introduces and summarizes the application of uranium complexes in dinitrogen activation and trans...

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