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Bismuth complexes with N/S coordination based metallopolymer as highly efficient photocatalyst for selective oxidation of styrene

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成果类型:
期刊论文
作者:
Wang, Qiuchen;Deng, Xiaoxu;Chen, Wenguang;Chen, Peng;Liu, Fei;...
通讯作者:
Chen, Peng(pchen3@gzu.edu.cn)
作者机构:
[Wang, Qiuchen; Liu, Fei; Chen, Peng] Guizhou Univ, Sch Chem & Chem Engn, Prov Guizhou Key Lab Green Chem & Clean Energy Te, Guiyang 550025, Guizhou, Peoples R China.
[Deng, Xiaoxu; Chen, Wenguang] Univ South China, Coll Elect Engn, Hengyang 421001, Hunan, Peoples R China.
[Yin, Shuang-Feng] Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Prov Hunan Key Lab Cost Effect Utilizat Fossil Fu, Changsha 410082, Hunan, Peoples R China.
通讯机构:
[Peng Chen; Fei Liu] P
[Shuang-Feng Yin] S
State Key Laboratory of Chemo/Biosensing and Chemometrics, Provincial Hunan Key Laboratory for Cost-effective Utilization of Fossil Fuel Aimed at Reducing Carbon-dioxide Emissions, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, Hunan, China<&wdkj&>Provincial Guizhou Key Laboratory of Green Chemical and Clean Energy Technology, School of Chemistry and Chemical Engineering, Guizhou University, Guiyang 550025, Guizhou, China
语种:
英文
关键词:
C3N3S3;Metallopolymer;Photocatalysis;Selective oxidation;Styrene
期刊:
Fuel
ISSN:
0016-2361
年:
2021
卷:
302
页码:
121127
基金类别:
This project was financially supported by Scientific and Technological Innovation Talents Team Project of Guizhou Province (NO.20185607), One Hundred Person Project of Guizhou Province (NO.20165655), Natural Science Project of Department of Education of Guizhou Province (NO.2017116), Innovation Group Project of Education Department in Guizhou Province (NO.2021010) and Natural Science Special Foundation of Guizhou University (No. X2020063 and X2019065)
机构署名:
本校为其他机构
院系归属:
电气工程学院
摘要:
Photocatalytic selective oxidation organic compounds to produce high additional value of products with air hold great promising in the chemical industry, but the photocatalyst often suffered from serious recombination of charge carriers, limited conversion efficiency, poor oxygen adsorption and stability. Here, a novel bismuth complexes with N/S coordination based metallopolymer (BiTMT) has been prepared by a facile wet-chemical method. It is confirmed that the weak interaction of Bi−N bonds not only acted as electron trapping site and charge ...

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