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Simultaneous determination of ultra-trace level 237Np and Pu isotopes in soil and sediment samples by SF-ICP-MS with a single column chromatographic separation

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成果类型:
期刊论文
作者:
Huang, Zhaoya;Ni, Youyi;Wang, Hai;Zheng, Jian*;Yamazaki, Shinnosuke;...
通讯作者:
Zheng, Jian;Long, Xinggui
作者机构:
[Uchida, Shigeo; Huang, Zhaoya; Zheng, Jian; Yamazaki, Shinnosuke] Natl Inst Quantum & Radiol Sci & Technol, Dept Radioecol & Fukushima Project, Inage Ku, 491 Anagawa, Chiba 2638555, Japan.
[Huang, Zhaoya; Long, Xinggui] China Acad Engn Phys, Inst Nucl Phys & Chem, Mianyang 621900, Sichuan, Peoples R China.
[Ni, Youyi] Peking Univ, Sch Phys, State Key Lab Nucl Phys & Technol, Beijing 100871, Peoples R China.
[Wang, Hai] Univ South China, Sch Nucl Sci & Technol, Hengyang 421001, Peoples R China.
[Sakaguchi, Aya] Univ Tsukuba, Ctr Res Isotopes & Environm Dynam, Tsukuba, Ibaraki, Japan.
通讯机构:
[Zheng, Jian] N
[Long, Xinggui] C
Natl Inst Quantum & Radiol Sci & Technol, Dept Radioecol & Fukushima Project, Inage Ku, 491 Anagawa, Chiba 2638555, Japan.
China Acad Engn Phys, Inst Nucl Phys & Chem, Mianyang 621900, Sichuan, Peoples R China.
语种:
英文
关键词:
Np-237;Pu isotope;Anion-exchange chromatography;SF-ICP-MS;Soil
期刊:
Microchemical Journal
ISSN:
0026-265X
年:
2019
卷:
148
页码:
597-604
基金类别:
JSPS KAKENHIMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of ScienceGrants-in-Aid for Scientific Research (KAKENHI) [JP17k00537, JP17H01874]; Grant of Fukushima Prefecture related to Research and Development in Radiological Sciences
机构署名:
本校为其他机构
院系归属:
核科学技术学院
摘要:
This work presents a method developed for simultaneous analysis of ultra-trace level Np-237 and Pu isotopes in soil and sediment samples by sector field inductively coupled plasma mass spectrometry (SF-ICP-MS). Pu-242 was used as a yield tracer for Np-237 as well as for Pu isotopes. A simple single chromatographic column packed with anion exchange resin (AG MP-1M) was used for the separation of Np-237 and Pu isotopes from the matrix elements and other potential interferences. The SF-ICP-MS measurement precision of the Np-237/Pu-242 atom ratio for sub-fg/mL level Np-237 and (PU)-P-242 was 0.97%...

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