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Nanoscale Rhodium(I) Based Metal-Organic Framework Demonstrating Intense NIR-II Luminescence for Bioimaging

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成果类型:
期刊论文
作者:
Wei, Wenxuan;Du, Yijing;Kang, Xiaomei;Liu, Yilin;Liu, Yujia;...
通讯作者:
Bu, WF;Zhu, SJ;Wang, J
作者机构:
[Wei, Wenxuan; Kang, Xiaomei; Liu, Yujia; Guo, Qian; He, Qun; Bu, Weifeng; Bu, WF; Liu, Yilin] Lanzhou Univ, Key Lab Nonferrous Met Chem & Resources Utilizat G, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.
[Wei, Wenxuan; Kang, Xiaomei; Liu, Yujia; Guo, Qian; He, Qun; Bu, Weifeng; Bu, WF; Liu, Yilin] Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China.
[Wei, Wenxuan; Zhou, Jin Yuan] Lanzhou Univ, Sch Phys Sci & Technol, Lanzhou 730000, Peoples R China.
[Zhu, Shoujun; Du, Yijing; Zhu, SJ] First Hosp Jilin Univ, Joint Lab Optofunct Theranost Med & Chem, Changchun 130021, Peoples R China.
[Zhu, Shoujun; Du, Yijing; Zhu, SJ] Jilin Univ, Coll Chem, Ctr Supramol Chem Biol, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China.
通讯机构:
[Bu, WF ] L
[Zhu, SJ ] F
[Wang, J ] U
Lanzhou Univ, Key Lab Nonferrous Met Chem & Resources Utilizat G, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.
Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China.
语种:
英文
关键词:
rhodium(I)-based nanoMOFs;NIR-II luminescence;Rh(I)Rh(I) interaction;vascular and tumorimaging
期刊:
NANO LETTERS
ISSN:
1530-6984
年:
2025
卷:
25
期:
11
页码:
4613-4620
基金类别:
National Natural Science Foundation of China [92161126, 52073130, 22101127]; National Natural Science Foundation of China [22YF7WA015, 21JR7RA468]; Science and Technology Program of Gansu Province
机构署名:
本校为通讯机构
摘要:
Although luminescent metal-organic frameworks (MOFs) have been widely reported, rare examples were found to emit in the second near-infrared (NIR-II, 1000-1700 nm) window. In this work, two nanoscale rhodium(I)-based MOFs (Rh-1@SDS and Rh-1@DSPE-PEG) have been controllably constructed in the aqueous dispersions of sodium dodecyl sulfate (SDS) and 1,2-distearoyl-sn-glycero-3-phosphoethanolamine-N-methoxy-poly(ethylene glycol) (DSPE-PEG), wherein micelle- and vesicle-like aggregates form, respectively, with high colloidal stability. The vesicular dispersion of Rh-1@DSPE-PEG exhibits intense NIR-...

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