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Nanoscale Rhodium(I) Based Metal-Organic Framework Demonstrating Intense NIR-II Luminescence for Bioimaging.

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成果类型:
期刊论文
作者:
Wei, Wenxuan;Du, Yijing;Kang, Xiaomei;Liu, Yilin;Liu, Yujia;...
作者机构:
[Bu, Weifeng; Wei, Wenxuan; Kang, Xiaomei; Liu, Yilin; Liu, Yujia; Guo, Qian; He, Qun] Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province, State Key Laboratory of Applied Organic Chemistry, and College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China
[Wei, Wenxuan; Zhou, Jin Yuan] School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, China
[Du, Yijing; Zhu, Shoujun] Joint Laboratory of Opto-Functional Theranostics in Medicine and Chemistry, First Hospital of Jilin University, Changchun 130021, China
[Du, Yijing; Zhu, Shoujun] State Key Laboratory of Supramolecular Structure and Materials, Center for Supramolecular Chemical Biology, College of Chemistry, Jilin University, Changchun 130012, China
[Wang, Jun] Hunan Province Cooperative Innovation Center for Molecular Target New Drug Study, School of Pharmaceutical Science, Hengyang Medical School, University of South China, Hengyang 421001, China
语种:
英文
关键词:
NIR-II luminescence;Rh(I)···Rh(I) interaction;rhodium(I)-based nanoMOFs;vascular and tumor imaging
期刊:
NANO LETTERS
ISSN:
1530-6984
年:
2025
机构署名:
本校为其他机构
摘要:
Although luminescent metal-organic frameworks (MOFs) have been widely reported, rare examples were found to emit in the second near-infrared (NIR-II, 1000-1700 nm) window. In this work, two nanoscale rhodium(I)-based MOFs (Rh-1@SDS and Rh-1@DSPE-PEG) have been controllably constructed in the aqueous dispersions of sodium dodecyl sulfate (SDS) and 1,2-distearoyl-sn-glycero-3-phosphoethanolamine-N-methoxy-poly(ethylene glycol) (DSPE-PEG), wherein micelle- and vesicle-like aggregates form, respectively, with high colloidal stability. The vesicular dispersion of Rh-1@DSPE-PEG exhibits intense NIR-...

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