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Adsorption of trace thorium(IV) from aqueous solution by mono-modified beta-cyclodextrin polyrotaxane using response surface methodology (RSM)

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成果类型:
期刊论文
作者:
Liu, Huijun*;Qi, Caixia;Feng, Zhiyuan;Lei, Lanlin;Deng, Shanxia
通讯作者:
Liu, Huijun
作者机构:
[Feng, Zhiyuan; Deng, Shanxia; Liu, Huijun; Qi, Caixia; Lei, Lanlin] Univ South China, Coll Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China.
通讯机构:
[Liu, Huijun] U
Univ South China, Coll Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China.
语种:
英文
关键词:
Cyclodextrin polyrotaxane;Thorium(IV);Response surface methodology (RSM);Adsorption isotherms;Thermodynamics
期刊:
Journal of Radioanalytical and Nuclear Chemistry
ISSN:
0236-5731
年:
2017
卷:
314
期:
3
页码:
1607-1618
基金类别:
Nature Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [11375084]; Nature Science Foundation of Hunan [2017JJ4046]; Hunan Provincial Innovation Foundation for Postgraduate [CX2017B523]
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
The adsorption of thorium(IV) was studied using a novel supramolecular polyrotaxane based on β-cyclodextrin derivatives. The effects of pH, contact time, Th(IV) initial concentration and adsorbents dosage on the adsorption of thorium(IV) by polyrotaxane were optimized using Box–Behnken design of response surface methodology. Analysis of variance and correlation coefficients showed that the predicted model was consistent with the experimental data well. The adsorption best fitted to the Langmuir model indicated that the adsorption process happ...

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