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The effect of entropy on the structure and aqueous durability of nanocrystalline rare-earth zirconate ceramics

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成果类型:
期刊论文
作者:
Xu, Min;Xia, Yue;Li, Haonan;Wu, Guanfeng;Zhao, Chengjie;...
通讯作者:
Xia, Y
作者机构:
[Xia, Yue; Li, Haonan; Zhao, Chengjie; Xu, Min; Wu, Guanfeng; Liao, Qian; Xia, Y; Wang, Hai] Univ South China, Sch Nucl Sci & Technol, Hengyang 421001, Peoples R China.
[Xia, Yue; Li, Haonan; Xu, Min; Wang, Hai; Liu, Longcheng; Li, Chunguang] Univ South China, R&D & Modeling Ctr Treatment & Disposal Radioact, Hengyang 421001, Peoples R China.
[Xia, Yue; Watabe, Hiroshi] Tohoku Univ, Cyclotron & Radioisotope Ctr, Sendai 9808578, Japan.
[Li, Yuhong] Lanzhou Univ, Sch Nucl Sci & Technol, Lanzhou 730000, Peoples R China.
通讯机构:
[Xia, Y ] U
Univ South China, Sch Nucl Sci & Technol, Hengyang 421001, Peoples R China.
语种:
英文
关键词:
Zirconate;High-entropy;Nanocrystalline;Aqueous durability
期刊:
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
ISSN:
0955-2219
年:
2025
卷:
45
期:
3
基金类别:
Research Foundation of Education Bureau of Hunan Province [21A0280]; China Scholarship Council; Ministry of Education of the People's Re-public of China
机构署名:
本校为第一且通讯机构
院系归属:
核科学技术学院
摘要:
A series of compositionally complex A2Zr2O7 nanocrystalline ceramics were successfully prepared using sol-gel and co-precipitation methods. The resultant ceramics possess a cubic defect fluorite structure, with the sol-gel method yielding an average grain size of approximately 50-70 nm, while the co-precipitation method result in an average grain size of about 40-60 nm. Leaching tests revealed that the smaller grain sizes are correlated with higher leaching rates. Furthermore, for ceramics with similar grain sizes, those with higher entropy values exhibited higher leaching rates. The increase ...

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