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Highly efficiently selective separation of zirconium from scandium by TRPO modified adsorbent

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成果类型:
期刊论文
作者:
Zhong, Yilai;Ning, Shunyan;Wang, Xinpeng;He, Chunlin;Fujita, Toyohisa;...
通讯作者:
Ning, SY
作者机构:
[Wang, Xinpeng; He, Chunlin; Fujita, Toyohisa; Zhong, Yilai] Guangxi Univ, Sch Resources Environm & Mat, State Key Lab Featured Met Mat & Life Cycle Safety, Nanning 530004, Peoples R China.
[Ning, Shunyan; Wei, Yuezhou; Hamza, Mohammed F.] Univ South China, Sch Nucl Sci & Technol, 28 Changsheng West Rd, Hengyang 421001, Peoples R China.
[Wei, Yuezhou] Shanghai Jiao Tong Univ, Sch Nucl Sci & Engn, 800 Dong Chuan Rd, Shanghai 200240, Peoples R China.
通讯机构:
[Ning, SY ] U
Univ South China, Sch Nucl Sci & Technol, 28 Changsheng West Rd, Hengyang 421001, Peoples R China.
语种:
英文
关键词:
Scandium zirconium;Adsorption separation;TRPO;DFT calculation;Column experiments
期刊:
Journal of Environmental Chemical Engineering
ISSN:
2213-3437
年:
2023
卷:
11
期:
3
页码:
109906
基金类别:
CRediT authorship contribution statement Yilai Zhong: Data curation, Writing – original draft. Shunyan Ning: Formal analysis, Writing – review & editing. Xinpeng Wang: Investigation. Chunlin He: Methodology, Conceptualization. Toyohisa Fujita: Supervision. Mohammed F. Hamza: Software. Yuezhou Wei: acquisition.
机构署名:
本校为通讯机构
院系归属:
核科学技术学院
摘要:
Scandium (Sc) and zirconium (Zr) often co-exists with each other and are difficult to separate effectively due to their similar behavior during separation. Herein, a series of adsorbents were synthesized by vacuum impreg-nation method for the separation of Sc and Zr. The results show that the Trialkylphosphine oxide silica-based modified adsorbent (TRPO/SiO2-P) has excellent adsorption selectivity (SFSc/Zr = 3694). It has fast adsorption and elution kinetics with equilibrium obtained within 30 min, and the adsorption matches the pseudo-second-order kinetic model and Langmuir isotherm model. Fo...

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