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Controlled morphological transition of ABC triblock copolymer aided by oleic acid via hydrogen bonding

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成果类型:
期刊论文
作者:
Nie, Xiaobo*;Jiang, Wei
通讯作者:
Nie, Xiaobo
作者机构:
[Nie, Xiaobo] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
[Jiang, Wei] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Jilin, Peoples R China.
通讯机构:
[Nie, Xiaobo] U
Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
语种:
英文
关键词:
Hydrogen bonding;Multicompartment micelles;Self-assembly;Supramolecular polymer;Triblock copolymer
期刊:
Colloids and Surfaces A: Physicochemical and Engineering Aspects
ISSN:
0927-7757
年:
2019
卷:
581
页码:
123839
基金类别:
This work was supported by Natural Science Foundation of Hunan Province (2017JJ3264). We are grateful to Professor Zhen Fang of Anhui Normal University for the help in some TEM testing.
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
A facile method is introduced to tune the aggregate morphologies of ABC triblock copolymer in selective media by combining the self-assembly and hydrogen bonding. Poly(styrene)-block-poly(1,4-butadiene)-block-poly(2-vinyl pyridine), abbreviated for PS-b-PBd-b-P2VP and used as an ABC triblock copolymer, self-assembles in toluene and methanol mixture to form discoid micelles with PBd as the disk containing part of PS domains in the core, other PS as bumps and P2VP as corona, respectively. When oleic acid (OA) is added in the assembly system, supr...

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