Efficient enantioselective michael addition of nitroalkenes catalyzed by a new surfactant-type thiourea organocatalyst in water

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作者信息关键词期刊信息会议信息基础信息归属信息摘要

成果类型：

期刊论文、会议论文

作者：

Hong Ying Zhang;Xue Ming Yan

通讯作者：

Yan, X. M.

作者机构：

[Yan X.M.] College of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, China

Hengyang Finace Economics and Industry Polytechnic, Hengyang 421001, China

[Zhang H.Y.] College of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, China, Hengyang Finace Economics and Industry Polytechnic, Hengyang 421001, China

通讯机构：

[Yan, X. M.] C

College of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, China

语种：

英文

关键词：

Asymmetric catalysis;Asymmetric Michael reaction;Organocatalysis;Surfactant-type catalyst

期刊：

Advanced Materials Research

ISSN：

1022-6680

年：

2014

卷：

1015

页码：

602-605

会议名称：

4th International Symposium on Chemical Engineering and Material Properties, ISCEMP 2014

会议时间：

28 June 2014 through 29 June 2014

出版者：

Trans Tech Publications Ltd

ISBN：

9783038352303

DOI：

10.4028/www.scientific.net/AMR.1015.602

机构署名：

本校为第一且通讯机构

院系归属：

化学化工学院

摘要：

A new surfactant-type bifunctional thiourea organocatalysts were synthesized. In the presence of 10 mol% PhCOOH, the Michael reaction of nitroalkenes with various nucleophiles could be catalyzed smoothly by this new organocatalyst in water at room temperature, giving the desired adducts in good yields with high diastereoselectivities (syn/anti=82/18->99/1)...

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Efficient enantioselective michael addition of nitroalkenes catalyzed by a new surfactant-type thiourea organocatalyst in water

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