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某尾矿库附近各土壤层对U(VI)的吸附特性

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成果类型:
期刊论文
论文标题(英文):
Adsorption characteristics of uranium in soil horizons near tailings impoundment area
作者:
杨升;张晓文;张利江;吴晓燕;李密;...
通讯作者:
Zhang, X.
作者机构:
[张利江; 黄倩文; 杨升] School of Resource & Environmental and Safety Engineering, University of South China, Hengyang, 421001, China
Key Laboratory of Radioactive Waste Treatment and Disposal, University of South China, Hengyang, 421001, China
[王亮] Hengyang Valin Steel Tube Co. Ltd., Hengyang, 421001, China
[张晓文; 李密; 吴晓燕] School of Resource & Environmental and Safety Engineering, University of South China, Hengyang, 421001, China, Key Laboratory of Radioactive Waste Treatment and Disposal, University of South China, Hengyang, 421001, China
通讯机构:
[Zhang, X.] S
School of Resource & Environmental and Safety Engineering, China
语种:
中文
关键词:
近地表处置;铀尾矿库;土壤剖面;静态吸附
关键词(英文):
Near-surface disposal;Soil profile;Static adsorption;U(Ⅵ);Uranium tailing impoundment
期刊:
环境工程学报
ISSN:
1673-9108
年:
2019
卷:
13
期:
10
页码:
2511-2520
基金类别:
51874180:国家自然科学基金 2017SYL05:南华大学双一流建设项目 2018KYY162:南华大学研究生科学基金资助项目
机构署名:
本校为第一且通讯机构
院系归属:
环境与安全工程学院
摘要:
针对南方某铀尾矿库附近棕红壤剖面中的淋溶层、淀积层和母质层等土层对铀的吸附机理和空间分布规律进行了探讨。采用比表面测定、X射线荧光、扫描电镜、傅里叶变换和X射线衍射等方法对各土层样的理化性质、结构和形貌进行了表征分析;采用静态吸附法考查了时间、U(VI)初始浓度、pH、温度、粒径等因素对各土层吸附U(VI)的影响;并使用热力学和动力学方程对吸附过程进行了模拟分析。结果表明,25℃下淋溶层和淀积层pH均为6.2、母质层pH为4.1时,其对U(VI)最大吸附量分别可达23.60、22.82和13.05 mg·g~(-1)。热力学和动力学拟合结果分别表明,各土层对U(VI)更符合Langmuir方程(R~2>0.999)和准二级动力...
摘要(英文):
In this study, the adsorption mechanism and spatial distribution of U(Ⅵ) in the eluvial, illuvial and parent material horizon of a brown-red soil profile near a Uranium tailing impoundment in South China were discussed. The physical and chemical properties of the soil horizons were characterized by using surface area measurement, X-ray fluorescence, scanning electron microscope, fourier transform infrared spectroscopy and X-ray diffraction. The effects of time, U(Ⅵ) initial concentration, pH, temperature, and particle sizes on U(Ⅵ) adsorptio...

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