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Developing diluted low-concentration electrolyte with a high anion-to-solvent ratio for high-voltage lithium metal batteries

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成果类型:
期刊论文
作者:
Li, Chengzong;Li, Yan;Wang, Yan;Bai, Fengwei;Chen, Xiang;...
通讯作者:
Li, T
作者机构:
[Li, T; Li, Tao; Li, Chengzong; Li, Yan; Bai, Fengwei; Wang, Yan] Univ South China, Sch Resource Environm & Safety Engn, Hengyang 421001, Peoples R China.
[Chen, Xiang] Tsinghua Univ, Dept Chem Engn, Beijing 100084, Peoples R China.
通讯机构:
[Li, T ] U
Univ South China, Sch Resource Environm & Safety Engn, Hengyang 421001, Peoples R China.
语种:
英文
期刊:
Journal of Materials Chemistry A
ISSN:
2050-7488
年:
2024
卷:
12
期:
14
页码:
8236-8243
基金类别:
National Natural Science Foundation of China [21808125]; National Natural Science Foundation of China
机构署名:
本校为第一且通讯机构
摘要:
Low-concentration electrolyte demonstrates significant advantages in terms of low cost, low viscosity, and high wettability. However, its high solvent ratio usually induces a fragile organic-rich solid electrolyte interphase (SEI), which is not compatible with high-voltage lithium metal batteries (LMBs). Herein, a screening rule for diluents has been established based on the electrostatic potential, which guides the rational design of diluted low-concentration electrolyte (DLCE) with a high anion-to-solvent ratio. Specifically, the anti-solvating power of a diluent is positively correlated wit...

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