期刊论文

Xie, Rui;Wang, Xiao-Feng

英文

Journal of Coordination Chemistry

0095-8972

2019

72

2

251-261

10.1080/00958972.2018.1564285

This work was financially supported by the National Science Foundation of China (Grant No.11375082), the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry (for Dr. X.-F. Wang), the NSF of Hunan Province (Grant No.2016JJ3105) and the Research Foundation of Education Bureau of Hunan Province (15B200 and17C1358). The authors would like to thank anonymous referees for helpful discussions on crystal structures. This work was financially supported by the National Science Foundation of China (Grant No.11375082), the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry (for Dr. X.-F. Wang), the NSF of Hunan Province (Grant No.2016JJ3105) and the Research Foundation of Education Bureau of Hunan Province (15B200 and17C1358).

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Two three-dimensional (3-D) chiral coordination polymers, [Cd(NDC)(DMF)] n (1 L and 1 D : H 2 NDC = 1,4-naphthalenedicarboxylic acid and DMF = N,N′-dimethylformamide), have been synthesized by introducing the rigid achiral dicarboxylic acid ligand under solvo-thermal conditions, without chiral template or additives. Both chiral Cd-CPs were characterized by single crystal X-ray crystallography, and structural analysis indicates that 1 L and 1 D are enantiomers based on the zigzag [Cd(COO) 2 (DMF)] n rod secondary building units, featuring the l...