作者机构：
[He W.-M.] School of Chemistry and Chemical Engineering, University of South China, Hengyang, 421001, China;[Cui X.] Engineering Research Centre of Molecular Medicine of Ministry of Education, Key Laboratory of Fujian Molecular Medicine, Key Laboratory of Precision Medicine and Molecular Diagnosis of Fujian Universities, Key Laboratory of Xiamen Marine and Gene Drugs, School of Biomedical Sciences, Huaqiao University, Xiamen, 361021, China
通讯机构：
[He, W.-M.; Cui, X.] E;Engineering Research Centre of Molecular Medicine of Ministry of Education, China
关键词：
processes.;SYNTHESIS;Green
摘要：
In 1998, Paul Anastas and John Warner defined 12 Principles of Green Chemistry, aiming at cleaner processes, safer products and increasing use of renewable rather than fossil resources. With the growing awareness of environmental issues, the international chemical community is driven to develop novel and environmentally friendly synthetic strategies for the replacement of inefficient and pollutional chemical processes. Delightedly, a lot of ecofriendly synthetic methodologies have been established over the past decades.
作者机构：
[He, Wei-Min; Lin, Ying-Wu; Chen, Jin-Yang] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China.;[Gui, Qing-Wen; Deng, Jie; Yan, Shan-Shu] Yangtze Normal Univ, Coll Chem & Chem Engn, Chongqing 408000, Peoples R China.;[Wu, Hong-Yu; Cao, Zhong] Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Changsha 410114, Hunan, Peoples R China.
通讯机构：
[He, W.-M.] S;School of Chemistry and Chemical Engineering, China
关键词：
Green chemistry;Cross-dehydrogenative coupling;Atom ecomnomy;Reusability;Electrochemistry
摘要：
An environmentally friendly method for the synthesis of 3-organylselenyl quinolones through the electrochemical cross-dehydrogenative coupling of 4-quinolones and diorganyl diselenides was developed. As a green, atom economic and self-separating process, the present reaction requires neither external oxidants nor electrolytes, forming a recyclable catalytic system.
作者机构：
[He, Wei-Min; Jiang, Jun] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.;[Xiao, Fang] Cent South Univ, Xiangya Sch Publ Hlth, Changsha 410078, Peoples R China.;[Wang, Leyong] Nanjing Univ, Sch Chem & Chem Engn, Key Lab Mesoscop Chem MOE, Nanjing 210023, Peoples R China.
通讯机构：
[Wei-Min He] S;School of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, China
关键词：
Green chemistry;Green solvent;Water;Solvent free;Purification
摘要：
Clean production, as an important part of green chemistry, has received great attention and considerable development in recent years. In this perspective article, we summarized some examples of (nearly) quantitative synthesis, clean separation and purification to emphasize clean production. These reactions were carried out by using eco-friendly solvents and the pure products could be easily obtained through clean procedures.
作者机构：
[郦瑜杰; 王志梅; 肖锡林] School of Resource & Environment and Safety Engineering, University of South China, Hengyang;421001, China;[张迪; 刘陈; 廖力夫] School of Chemistry and Chemical Engineering, University of South China, Hengyang;Key Laboratory of Hengyang for Health Hazard Factors Inspection and Quarantine, University of South China, Hengyang;[郦瑜杰; 张迪; 刘陈; 王志梅; 廖力夫; 肖锡林] 421001, China
通讯机构：
School of Chemistry and Chemical Engineering, University of South China, Hengyang, China
关键词：
燃料电池;增湿;电化学;低湿度;高分子化合物
摘要：
通过向阳极催化层中添加高分子化合物亲水剂,制备了一种具有自增湿能力的膜电极。考察了亲水性高分子化合物的种类、相对湿度（RH）以及电池温度对膜电极自增湿性能的影响,并初步探索了膜电极的自增湿机理。结果表明,以羧甲基纤维素（CMC）为保水剂的膜电极表现出最好的低湿度性能;膜电极的自增湿性能受相对湿度影响不大,但随着温度的升高,其性能先升高后降低;在电池温度为60℃、20%RH、206 k Pa条件下,以羧甲基纤维素为保水剂的膜电极在0. 6 V的电流密度为900 m A/cm2,是空白膜电极的1. 8倍。
摘要：
OBJECTIVE: Type 1 diabetes (T1D) results from dysfunction of pancreatic islets beta cells. Recent studies supported that endoplasmic reticulum (ER) stress takes an important role in pancreatic beta cell excessive loss, resulting in T1D. Here, we aimed to review the relationship between ER stress and T1D. Additionally, we also reviewed the potential mechanisms underlying ER stress mediated T1D. DATA SOURCES: This review was based on the articles from PubMed databases up to July 2019, with the following keywords: "endoplasmic reticulum stress", "inflammation", "autoimmunity", and "type 1 diabetes". STUDY SELECTION: Original articles and critical reviews on the topics were selected and carefully analyzed. RESULTS: Studies have shown that severe ER stress is directly involved in the pancreatic beta cells destruction and pathogenesis of T1D. CONCLUSIONS: ER stress plays a key part in pancreatic beta cells and T1D, which will help in developing new effective therapeutics for T1D.
作者：
Song Huan*;Wang Lin;Wang Hong-Qing;Shi Wei-Qun
期刊：
无机材料学报,2020年35(1):65-72 ISSN：1000-324X
通讯作者：
Song Huan
作者机构：
[Song Huan; Wang Hong-Qing] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.;[Wang Lin; Shi Wei-Qun] Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China.
通讯机构：
[Song Huan] U;Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
作者机构：
[Duan, Chongxiong] Foshan Univ, Sch Mat Sci & Energy Engn, Foshan 528231, Peoples R China.;[Yu, Yi; Xi, Hongxia; Zhang, Xuelian; Li, Libo; Xiao, Jing] South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Peoples R China.;[Wu, Junliang] South China Univ Technol, Sch Environm & Energy, Guangzhou 510006, Peoples R China.;[Yang, Pengfei] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
通讯机构：
[Xi, Hongxia; Wu, Junliang] S;South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Peoples R China.;South China Univ Technol, Sch Environm & Energy, Guangzhou 510006, Peoples R China.
关键词：
metal-organic frameworks;water-based routes;industrial Production
摘要：
Although metal-organic frameworks (MOFs) show numerous advantages over other crystalline materials, their industrial relevances have been impeded owing to their many drawbacks such as environmental impacts and economic costs of their synthesis. A green preparation pathway could greatly reduce the environmental costs, energy, and the need for toxic organic solvents, and consequently reduce the production cost. Thus, the most desirable synthesis route is the replacement of harsh organic solvents with aqueous solutions to abate environmental and economic impacts. This review summarizes recent research advancements of water-based routes for MOF synthesis and gives a brief outline of the most prominent examples. The challenges and prospects of the commercialization of promising MOFs in the future are also presented. This study aims to offer necessary information regarding the green, sustainable, and industrially acceptable fabrication of MOFs for their commercial applications in the future.
作者机构：
Department of Chemistry, Hunan University of Science and Engineering, Yongzhou, China;Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha, China;[Ying-Wu Lin] School of Chemistry and Chemical Engineering, University of South China, Hengyang, China;[Dong-Hong Yu] Department of Chemistry and Bioscience, Aalborg University, Aalborg, East, Denmark;[Wei-Min He] Department of Chemistry, Hunan University of Science and Engineering, Yongzhou, China<&wdkj&>Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha, China
通讯机构：
[Wei-Min He] D;Department of Chemistry, Hunan University of Science and Engineering, Yongzhou, China<&wdkj&>Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha, China
关键词：
URANYL;OXIDATION;GROUND-STATE;OXYGEN
摘要：
Sulfur-containing organic compounds such as sulfides,sulfoxides and sulfones, have played significant roles in the fields of organic synthesis, pharmaceuticals, and agrochemicals.The selective oxidation of the parent sulfides has been considered as one of the most straightforward methods for the construction of sulfoxides and sulfones.Therefore, a plethora of oxidative systems have been developed for the selective oxidation of sulfides, in which strong oxidants like organic/inorganic peroxides, hypervalent iodines, highpressure oxygen, were required with/without the catalysis of transition metals.In the point view of green chemistry, the application of atmospheric molecular oxygen as an oxidant for the selective oxidation of sulfides under mild conditions is highly desired.
作者机构：
[何卫民] Department of Chemistry, Hunan University of Science and Engineering, Yongzhou, Hunan 425100, China;Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha, 410114, China;[林英武] School of Chemistry and Chemical Engineering, University of South China, Hengyang, Hunan 421001, China;[彭莎] Department of Chemistry, Hunan University of Science and Engineering, Yongzhou, Hunan 425100, China, Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha, 410114, China
通讯机构：
[He, W.] D;Department of Chemistry, Hunan University of Science and Engineering, Yongzhou, Hunan, China
