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TsCl-promoted sulfonylation of quinoline N-oxides with sodium sulfinates in water

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成果类型:
期刊论文
作者:
Peng, Sha;Song, Yan-Xi;He, Jun-Yi;Tang, Shan-Shan;Tan, Jia-Xi;...
通讯作者:
He, Wei-Min
作者机构:
[He, Wei-Min; Tang, Shan-Shan; Song, Yan-Xi; Peng, Sha] Hunan Univ Sci & Engn, Dept Chem, Yongzhou 425100, Peoples R China.
[He, Jun-Yi; Cao, Zhong] Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Changsha 410114, Peoples R China.
[Tan, Jia-Xi] Hunan Univ Sci & Technol, Sch Chem & Chem Engn, Xiangtan 411201, Peoples R China.
[Lin, Ying-Wu] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
通讯机构:
[He, Wei-Min] H
Hunan Univ Sci & Engn, Dept Chem, Yongzhou 425100, Peoples R China.
语种:
英文
关键词:
Quinoline N-oxides;2-Sulfonylquinolines;Sodium sulfinates;Sulfonylation;In water
期刊:
中国化学快报:英文版
ISSN:
1001-8417
年:
2019
卷:
30
期:
12
页码:
2287-2290
基金类别:
We are grateful for financial support from the Hunan Provincial Natural Science Foundation of China (No. 2019JJ20008 ).
机构署名:
本校为其他机构
院系归属:
化学化工学院
摘要:
An eco-friendly protocol for the synthesis of various 2-sulfonyl quinolines/pyridines through sulfonylation of heteroaromatic N-oxides with sodium sulfinates in water at ambient temperature under metal- and oxidant-free conditions has been developed. The mild reaction conditions, high reaction efficiency, operational simplicity, short reaction time and remarkable functional-group compatibility make the developed protocol very attractive f...

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