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Two temperature-induced isomers of metal-carboxylate frameworks based on different linear trinuclear Co3(RCOO)8 clusters exhibiting different magnetic behaviours

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成果类型:
期刊论文
作者:
Wang, Xiao-Feng;Zhang, Yue-Biao;Xue, Wei;Qi, Xiao-Lin;Chen, Xiao-Ming*
通讯作者:
Chen, Xiao-Ming
作者机构:
[Chen, Xiao-Ming; Qi, Xiao-Lin; Zhang, Yue-Biao; Xue, Wei; Wang, Xiao-Feng] Sun Yat Sen Univ, Sch Chem & Chem Engn, State Key Lab Optoelectron Mat, MOE Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China.
[Zhang, Yue-Biao] Univ S China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
通讯机构:
[Chen, Xiao-Ming] S
Sun Yat Sen Univ, Sch Chem & Chem Engn, State Key Lab Optoelectron Mat, MOE Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China.
语种:
英文
期刊:
CrystEngComm
ISSN:
1466-8033
年:
2010
卷:
12
期:
11
页码:
3834-3839
基金类别:
NSFCNational Natural Science Foundation of China (NSFC) [20821001, 90922031]; 973 ProjectNational Basic Research Program of China [2007CB815302]
机构署名:
本校为其他机构
院系归属:
化学化工学院
摘要:
A pair of structurally isomeric metal-carboxylate frameworks (MCFs) with an identical formula of [Me 2 NH 2 ] 2 [Co 3 (1,4-bdc) 4 ]·4DMF (1 and 2, Me 2 NH 2 = protonated dimethylamine, 1,4-bdcH 2 = 1,4-benzenedicarboxylic acid and DMF = N,N′-dimethylformamide) have been synthesized from identical reactants at 160 °C and room temperature, respectively. Although both compounds feature the same bcg net (a uninodal eight-connected net) based on the Co 3 (OOCR) 8 clusters as eight-connected nodes, the isomers exhibit different magnetic behaviours...

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