Co0.76Cu0.74[Fe(CN)6]·7.5H2O was prepared as a powder by a chemical co-precipitation method. The powder X-ray diffraction patterns were indexed to the typical face-centred cubic structure with the lattice parameter a 10.55(2) Å. The temperature dependence of the χ-1 curve obeys the Curie-Weiss law (χ = C/(T-θ)) in the temperature range of 180-300 K. According to Curie-Weiss law, the calculated θ value is-54.82 K. In the paramagnetic state at 300 K, the effective magnetic moment (μeff = (8χT)1/2) is 3.58 μB per formula unit. The calcula...