Dalian Institute of Chemical Physics, Chinese Academy of SciencesChinese Academy of Sciences
机构署名:
本校为其他机构
院系归属:
化学化工学院
摘要:
Rhodium(III)-catalyzed oxidative olefination of N-(1-naphthyl)sulfonamides has been achieved at the peri position. Three categories of olefins have been successfully applied. Activated olefins reacted to afford five-membered azacycles as a result of oxidative olefination-hydroamination. Unactivated olefins reacted to give the olefination product. 2-fold oxidative C-C and C-N coupling was achieved for...