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Rh(III)-Catalyzed Oxidative Olefination of N-(1-Naphthyl)sulfonamides Using Activated and Unactivated Alkenes

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成果类型:
期刊论文
作者:
Li, Xuting;Gong, Xue;Zhao, Miao;Song, Guoyong;Deng, Jian;...
通讯作者:
Li, Xingwei
作者机构:
[Song, Guoyong; Li, Xuting; Gong, Xue; Zhao, Miao; Li, Xingwei] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China.
[Li, Xuting; Deng, Jian] Univ S China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
通讯机构:
[Li, Xingwei] C
Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China.
语种:
英文
期刊:
Organic Letters
ISSN:
1523-7060
年:
2011
卷:
13
期:
21
页码:
5808-5811
基金类别:
Dalian Institute of Chemical Physics, Chinese Academy of SciencesChinese Academy of Sciences
机构署名:
本校为其他机构
院系归属:
化学化工学院
摘要:
Rhodium(III)-catalyzed oxidative olefination of N-(1-naphthyl)sulfonamides has been achieved at the peri position. Three categories of olefins have been successfully applied. Activated olefins reacted to afford five-membered azacycles as a result of oxidative olefination-hydroamination. Unactivated olefins reacted to give the olefination product. 2-fold oxidative C-C and C-N coupling was achieved for...

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